Stress corrosion cracking of sensitized type 304 stainless steel in high temperature chloride solutions l. Stress corrosion cracking of sensitized type 304 stainless. Chloride stress corrosion cracking and 316 stainless steel moltenmetal chemical 20 jul 11 07. The combined action of tensile stress with corrosive environment can lead to chloride stress corrosion cracking cscc. Resistance to chloride stress corrosion cracking is correlated with nickel content, with the 25% nickel ss 904l alloy, showing improved resistance compared to an 8% nickel alloy like type 304 stainless steel. A corrosive medium especially chloride bearing or hydrogensulphide h 2 s media. Chloride stress corrosion cracking cscc is a type of intergranular corrosion. Temperature is a significant environmental factor affecting cracking. Stress corrosion cracking is a general term describing stressed alloy failures appearing as cracks in the stainless steel that occur in corrosive environments. Chlorideinduced stress corrosion cracking of 316 stainless. External chloride stress corrosion cracking ecscc of insulated austenitic stainless steels e. Pitting corrosion starts when the chromiumrich passive oxide film on 316 tubing breaks down in a chloride rich environment.
Chloride stress corrosion cracking inspectioneering. It occurs in austenitic stainless steel under tensile stress in the presence of oxygen, chloride ions and high temperature. Conventional stainless steels such as 304l and 316l are susceptible to chloride stress corrosion cracking ssc under certain conditions. This paper described the mechanism of chlorideinduced stress corrosion cracking of oil tube as a result of. Chloride stress corrosion cracking in austenitic stainless steel. Clscc chloride stress corrosion cracking mechanism china. Incoloy 825 is superiorly immune to stainless steel grade 316 in the chloride media due to larger content of nickel. Th e presenc e of interna l stres s shoul d alway s be taken into accoun t whe n decidin g the magnitud e of exter. The mechanism of chloride stress corrosion cracking clscc is complex and the current understanding is discussed in section 5 of this report. Sour service limits of dualcertified 316316l steel twi. Generally more resistant than 304 in range of atmospheric environments and many corrosive media due to the increased chromium and molybdenum content. Hot wall effects, as in reboiler tubing heated by steam will make the id of the. Resistance of the ss 904l alloy is further aided by presence of 4. Drop evaporation test method, author steinsmo, u and drugli, j m, abstractnote stress corrosion cracking scc of chloride exposed stainless steels under evaporative conditions has for long been recognized as a factor that needed special attention.
Pdf stress corrosion cracking of type 316 and 316l. Pitting corrosion of tubing usually is readily recognized. Stress corrosion cracking of weldments of aisi type 316. Chloride stress corrosion cracking clscc is one the most common reasons why austenitic stainless steel pipework and vessels deteriorate in the chemical processing and petrochemical industries. Stress corrosion cracking austenitic stainless steels are susceptible to stress corrosion cracking scc in halide environments. Chloride stress corrosion cracking clscc is a type of stress corrosion cracking scc and is one of the most well known forms of scc in the refining and chemical processing industries. This mode of attack is termed stress corrosion cracking scc. The stress may be applied, as in a pressure system, or it may be residual arising from. Stress corrosion cracking scc is a common issue with many specialty alloys. Essentially clscc involves a combination of the electrochemistry of metal dissolving over a highly localised area, i. Surface temperature matters it is important to know the actual surface temperature of the metal in contact with the process environment. Chloride stress corrosion cracking in austenitic stainless steel is characterized by the multibranched lightning bolt transgranular crack pattern. Cold worked austenitic stainless steel type 316 and 316l were studied in order to obtain their effects on scc crack growth rates in 288 and 325 c.
While no stainless steel can be completely immune, swageloks alloy 316 stainless steel fittings have performed exceptionally well in testing. Stress corrosion cracking scc was observed for the first time on the primary loop recirculation plr piping made of type 304 stainless steels ss in the u. Scc will occur when stainless steels are subjected to tensile stress, while in contact with solutions containing chlorides. Chloride induced stress corrosion cracking ciscc of stainless steel reactor components has occurred when three elements are all present. The combination of tensile stress and a specific corrosive environment can crack stainless steels.
Corrosion of unprotected carbon steel occurs even inside reinforced. Higher temperatures reduce the permissible chloride level. The stress corrosion cracking scc of aisi 304 and aisi 316 austenitic stainless steels in 0. This study is to identify factors responsible for loss of production due to problems in plant and equipment. Mechanisms of stresscorrosion cracking asm international. Or a structure under static tensile stress, much below the yield stress, in contact with corrosive environment may fail due to scc. Stress corrosion cracking scc is characterized by cracks propagating either transgranularly or intergranularly along grain boundaries. There are several types of stress corrosion cracking scc, for example, chloride induced scc and h 2 sinduced scc. Chlorine and chloride are different forms of the same element but with vastly different effects on stainless steel. Corrosion under insulation cui is a severe problem for 304 stainless steel pressure vessel. The presence of chloride in the eds spectrum also confirms the contribution of cl in pitting corrosion of the protective layer of 316 stainless steel plates. Austenitic steels of type astm 304 and 316 austenitic steels have limited resistance to stress corrosion cracking scc, even at very low chloride contents and temperatures.
Effects of chloride and oxygen on stress corrosion cracking. Parkins department of metallurgy and engineering materials, the university, haymarket. Stress corrosion cracking is a failure mechanism that is caused by environment, susceptible material, and tensile stress. The most common type of stress corrosion cracking in stainless steels occurs in chloride environments, which will be the focus of this discussion. The ss 904l alloy contains a combination of chromium and molybdenum which produces an improved level of resistance to pitting and crevice corrosion by chlorides compared to ss 316 stainless steel. The stress corrosion cracking of type 316 stainless steel in. The presence of fe, cr and o can be attributed to the corrosion products of s.
Scc is often associated with chlorides, but can also occur with caustics and other corrosive media. Corrosion resistance stress corrosion cracking 2205 is a cost effective solution for many applications where 300 series stainless steels are susceptible to chloride stress corrosion cracking scc. Although the phenomena of stress corrosion cracking is known to occur in 316l stainless steel in chloride environments, there is little knowledge regarding the incubation stage, i. The ss 904l alloy contains a combination of chromium and molybdenum which produces an improved level of resistance to pitting and crevice corrosion by. With a nickel content of 25%, 904l has proven to be a good alternative to most conventional stainless steels. It can lead to unexpected sudden failure of normally ductile metal alloys subjected to a tensile stress, especially at elevated temperature. Susceptibility assessment criteria for chlorideinduced. Stress corrosion cracking behavior of nickel base alloys. Cold work of materials, dissolved oxygen and chloride in water are crucial factors that accelerate the stress corrosion cracking scc crack growth rate of stainless steel in high temperature water. The most common environmental exposure condition responsible for scc of stainless steels is the presence of chlorides.
Although the type 316 alloy is somewhat more resistant to scc than the 18 cr8 ni alloys because of the molybdenum content, they still are quite susceptible. Table3cooling water analysis stress corrosion cracking scc is the progressive cracking of metals and alloys caused by the combined effect of sccprone microstructure, temperature, pressure and environments. The observed crack propaga tion is the result of the combined and synergistic interaction of mechanical stress and corrosion re actions. Individual shallow pits, and in later stages, deep and sometimes connected pits can be seen with the unaided eye. Parkins department of metallurgy and engineering materials, the university, haymarket lane, newcastle upon tyne ne1. Three underlying factors must be present to cause scc. Assessment of susceptibility to chloride stress corrosion. Chloride stress corrosion cracking and 316 stainless steel. Stainless steel provides both strength and corrosion resistance inside the concrete, providing a long, maintenancefree service life of the structure. Mechanism of chloride stress corrosion cracking of austenitic. Stresscorrosion cracking scc is a term used to describe service failures in engineering materials that occur by slow, environmentally induced crack propagation.
The most common type of stress corrosion cracking in stainless steels occurs in chloride environments, which will be the focus of. The micrograph on the left x300 illustrates scc in a 316 stainless steel chemical processing piping system. Oct 21, 2019 chloride stress corrosion cracking cscc is a type of intergranular corrosion. Although the alloys 316 and 317l are somewhat more resistant to scc than the 18 cr8 ni alloys because of their molybdenum content, they still are quire susceptible. C are not recommended for 304 or 316 as they are at risk of sudden failure from chloride stress corrosion cracking. Transgranular stress corrosion cracking of 316 l stainless. Chloride stress corrosion involves selective attack of a metal along its grain boundaries.
Pitting and crevice corrosion of offshore stainless steel. Corrosion of stainless steel 316 l with time in various. Deterioration by clscc can lead to failures that have the potential to release stored energy andor hazardous substances. In all cases of failure by stress corrosion cracking, the following three factors must be present. Stress corrosion cracking of type 316 and 316l stainless. Whenever stainless steel is exposed to chloride concentrations and stress levels, chloride stress corrosion cracking cscc can occur. Chlorideassisted stresscorrosion cracking in type 316. This form of corrosion is controlled by maintaining low chloride ion and oxygen content in the environment and use of lowcarbon steels. Subject to pitting and crevice corrosion in warm chloride environments, and to stress corrosion cracking above about 122f 50c. Corrosion resistance of stainless steels corrosion in concrete corrosion problems are not limited to outside surfaces. Corrosion of stainless steel 316 l in various aqueous salt solutions nawal muhammad dawood collage of materials engineering babylon university abstract the change with time in the corrosion rate and corrosion current density on an austenitic stainless steel 316 l electrode in various aqueous salt solutions have been. Pitting corrosion starts when the chromiumrich passive oxide film on. Elevated stress susceptible material corrosive environment surface contamination by atmospheric chlorides sufficient humidity epri has a multiyear project to. Corrosion of this type has been extensively studied and affects almost all metal alloys, including the austenitic grades of stainless steel used in brewing.
The surface concentration of hydrogen, oxygen, the hydroxide, and chloride. Jan 22, 20 stress corrosion cracking is a failure mechanism that is caused by environment, susceptible material, and tensile stress. Stress corrosion cracking of aisi 304 and aisi 316. The pitting and stress corrosion cracking of a stable austenitic stainless steel in aqueous chloride environments were investigated using a secondary ion mass spectrometer as the primary experimental technique. Temperature and corrosion rate more complex than you. It can be concluded that the formation of the pits and the presence of stress can lead to clscc failure of plates. Olaseinde, comparative study of the effect of temperature on the corrosion behavior of 2205 duplex stainless steel and 316 austenitic stainless steel in acidic chloride environment, advances in materials physics and chemistry 5, 185 190 2015. Stress corrosion cracking facts and how to reduce the. It is found that the stress vs timetofailure curves for both alloys are divided into three regions that are dominated by either stress, scc, or. This paper described the mechanism of chloride induced stress corrosion cracking of oil tube as a result of improper material selection and lack of maintenance.
Susceptibility to stress corrosion cracking of 254smo ss. Stress corrosion cracking in co2 compressor intercooler ijert. Chloride stress corrosion cracking in austenitic stainless. Facts in brief about stress corrosion cracking scc stress corrosion cracking scc is characterized by cracks propagating either transgranularly or intergranularly. Assessment of the corrosion, stress corrosion cracking and. Stress corrosion cracking facts and how to reduce the risk. Th e presenc e of interna l stres s shoul d alway s be taken into accoun t. Although no stainless steel grade is totally immune. Fourpoint bend testing on parent and welded dualcertified 316316l stainless steel, to iso 151563. Influence of high temperature on corrosion behavior of 304. It can be detrimental to austenitic stainless steels, one of the main reasons these steels are not considered a cureall for corrosion problems.
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